Hi csd, seeing as your gutting it completely it may be possible to release the refrigerant in a more safe and controlled manor. I was just afraid you were going to drill a hole anywhere and get a nasty surprise with the refrigerant escaping. Like I mentioned before the system will be under pressure if it's full of gas, the pressure will vary depending on ambient temperature and the exact gas enclosed, pressures could be upto and beyond 100psi. If it's a regular modern(ish) fridge it probably wont contain any hydrocarbons which contain butane and propane, highly flammable! some oldies contain ammonia. If modern it may contain r134a or r404a or similar these wont cause to much of a risk but ammonia is rather nasty if inhaled. Best thing I guess would be to look on the back where the compressor is and find the smallest copper pipe there is, it will probably be a few millimeters in diameter and brazed to long cylindrical tube, put some goggles on and a glove and chop the tiny pipe with a pair of side cutters, there will be a bit of a pop and the gas will come out with a drop of oil and maybe some liquid refrigerant. Leave the fridge for 10mins and have a drink while it flows out, best done outside.
I would like to add that in most countries it's highly illegal to release refrigerant into atmosphere and wont help global warming too much, but saying illegal, well, i don't think it matter much on this forum hey
Sorry to go on and on but I have seen many people damaged by refrigerants. If you get stuck on what pipe to cut post a good close picture of the fridge at the back where all the pipes are and I will have a look for you, may also be worth checking the model plate on the fridge and seeing what gas it has in there and how much.
Once again, sorry to go on, im happy to help further if you not sure.