When you think the plant is ready.
To get a better answer, you'd do well to share:
Pics (this, if nothing else)
What, if any, training you've been doing
Strain
Others might also want to know things like what exact light, soil mixture, feeding schedule, and such, but for this that's probably overkill.
As far as I can tell, there's no hard & fast rule about when to switch to 12/12, beyond when the plant is ready, and if it's ready has so many "it depends" on it that it's hard to just blanket say. To me, once my chosen amount of colas are trained to where I want them, equal in height, and the plant is solid (healthy), that's when I flip. That said, I use tents, so I also have to keep an eye on canopy height. The plant will grow 1 to 1.5 times again in flower, so that's another factor you can use to decide when to flip; when it's 1.5 times short of where you want to finish.