Not really that I can think of.. Well distilled water is a safe 7.0, and tomato juice is usually pretty close to 4.1-4.2, but theres no point in going beyond droplet tests if you're going to calibrate like that..
I'll look into possible solutions using distilled water and common pills or something else standardized/replicable though..
There is a hole in your bucket for a diy solution though given the fact that you need a trustworthy reading to calibrate a solution to calibrate your meter..