What solution are you using?
The vinegar probably dissoved the calcium deposits on the probe, got it working for you.
The KCI is storage solution
Method 1
Soak the electrode in a 0.4 molar concentration of HCl (hydrochloric acid) for 10 minutes, then rinse the electrode with deionized or distilled water. This should remove any organic protein from the glass electrode and the surface of the reference electrode.
Method 2
Soak the electrode in a 3.8 or 4.0 molar KCl (potassium chloride) solution heated to 50°C for 1 hour. Allow the KCl solution to cool down to room temperature, then rinse the electrode with deionized or distilled water. This will open and clean the reference electrode of all contaminants.
Method 3
Soak the electrode in a 4.01 pH buffer solution , heated to 50°C for 1 hour. Allow the buffer to cool down to room temperature, then rinse the electrode with deionized or distilled water. This will open and clean the reference electrode.
Method 4
For protein removal, soak the pH electrode in contact lens enzymatic cleaner solution overnight. The enzymes will remove proteins from glass and plastic.
Storage
Note:
never store your PH electrode in distilled water.
Bluelab uses 4M KCI, Apera uses 3M KCI, others use 1M KCI solution, proper chemical makes it read faster, more accurately and extends service life.
It is also possible to use pH 4 reference solution, if you don't have KCI for storage