CREE CXA 3000°K/80CRI spectrum analysis.

anomuumi

Member
Bravo Mr. SDS, excellent thread once again and absolutely the best explanation I have seen so far on the subject! Knna would approve too :)

One question though regarding the CXA and white leds in general, isn't there a shift in the spectral distribution with varying drive current/voltage/tJ? How much would you estimate the shift being with a CXA 3070 driven at 350mA and 1400mA? I guess we would need spectroradiometer data for that... But curious anyways.

Thank you so much for everything you have written here!

Supra, the digitizing isn't hard at all, I'm just not too sure if I can trust those SDP curves enough to use so much time and effort for a number that can throw 10% in any direction... I sure hope that Santa would bring me a spectroradiometer for christmas :D
 

stardustsailor

Well-Known Member
So now ...

We know ..

1) λ (nm ) / 119,708 * Φ (Radiant Power in W) = umoles/sec
2) Absorptance Y values (factor ) for PAR range (400-700 nm )
3 ) Relative Quantum Yield Y values for PAR range ...

Our led of 1 Watt Φ at 480 nm ,outputs 4 umols /sec
of which a potential maximum of 2,53 umols /sec is/ can be absorbed and utilised to drive photosynthesis .
(By quanta numbers..Remember ? )


No matter if one plant radiated or one thousand of them ...
The maximum potential photosynthetic quanta flux of that led
is 4 umols/sec * 0.92 absorptance factor *0.69 RQE


For 8 quantas used ,plants "break " one CO2 molecule into Carbon and Oxygen ,as gas ..
Or the plants need ~8 quantas (here the numbers ! ) for evey molecule CO2 to be
processed .as a direct result of photosynthesis .

Make them 10 ...
The quantas ...
To make our lives easier and allow for some " slack " there ...
So ,it takes ten photon's excitation energy ,the whole CO2= C + O2 "separation " thing ..


2,53 umoles per sec / 10 =

0,253 umoles of CO2 processed per second ( ideally or better yet " potentially " )
0,000000253 moles * 22,4 lt = 0.00000568 lt = 0.0056 ml of CO2 processed per second ...
Maximum and ideally ,thus " potentially " .... )

A blue led outputing 1 Watt of 480 nm light ,
has a Photosynthetic Potential of 0,253 umolsCO2/sec per Radiant Watt ..

Various 480 nm blue leds will have the exact same Photosynthetic Potential ,for it's wavelength dependant ....
But they will have different Photosynthetic Potential Efficiencies .
Photosynthetic Potential
Efficiency = Photosynthetic Potential / ( If*Vf )



Ok ...

What about white leds ?

Or before that ....
What is the Quanta * RQE* Absorptance per nm ?

That is :
" For 1 Watt or Radiant Power per nanometer ,the number of Quanta * RQE* Absorptance ...."

It 's PAR's Photosynthetic Potential or PAR Quantum Efficiency.

PAR Quanta  Efficiency per wl.JPG

1 Watt radiated at every given nanometer ,will be equal a x number of quanta per sec .
Multiplied with absorptance per wl and RQE per wl ,that graph comes up ....

Photon Flux per wl ,per W x Absorptance x RQE

4 ,for example ,means that at that given wl ( i.e. ~588 ) 1 watt of light ,will produce
4umoles/sec of photosynthetic potential light flux ...

It combines light physics with plant biology ...
What "light" has to give "by nature" (quanta numbers ) and how plants can ultimately use it ..
(absorb and utilise )

The photosynthetic max potential of PAR range ...
 
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stardustsailor

Well-Known Member
According to Mr Flux method, the Vero 4000K curve is 325 LER with 13% blue. At 1.4A (Tj 50C) it would be 37.1% efficient. Of course there a few problems with that measure. It is using the minimum numbers, which Mr Flux pointed out is more beneficial to the CXA than the Vero line, and Tj 50C might not be realistic in some applications at 1.4A.

It would be interesting to see how the SDS method compares. If a bunch of us can learn how to digitize these curves, we can share the burden :)
http://www.edn.com/design/analog/4410588/Digitize-graphical-data-easily-and-accurately


"Use the “Curve Point”
tool to manually insert points on the curve that are not automatically detected"

Better use this only ,all the way ..
Vey easy,simple and powerful free software ..
If version 5.1 does not work ,up one step in download folder to download an older version .
(I use 4.1 )

Results are amazing and super precise if graph is accurate and in usable state/ form ..
 

stardustsailor

Well-Known Member
And back to the CXA again .....
For its LPP and PPE ( Light Photosynthetic Potential & Photosynthetic Potential Efficiency )
.......
cxa LPP per w per nm 2.JPG


The blue curve line is PAR PPE ( or Photosynthetic-Active-Radiation-Quantum-Efficiency) .

The orange curve represents the rel.Power y value of CXA 3000K 80 CRI ,turned into umoles pwer wl ,
and then multiplied by Absorptance and RQE ....

λ / 119,708 * y Rel.PWR * Absorptance * RQE

That curve it combines what is given ('quanta" emitted by the device ), with what plants can ultimately use ...

The blue curve ,finally describes the best potential rel.specta for photosynthesis ...
 
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stardustsailor

Well-Known Member
The CXA 3070 Z4 3000K 80 CRI ,at 2000mA ,Tc =45 C
With a rad efficiency of 32,97% and a junction operating at ~87C
has a LPPE of 0,1207 umols/sec CO2 / electrical Watt ....
..... x 22.4 lit =
~0,003 ml oF CO2 per sec ....

That is 9,733 liters of CO2 per Hour ...

Per Watt ...
x 78 electrical Watts = ~760 lts of CO2 per Hour ...
760/22.4 =~34 moles of CO2 * 12 gram/mole for C = 407 grams of C processed per hour .

That is the max photosynthetic potential of that CXA chip ...
It can support photosynthetic yields / rates ,up to 400 grams of Carbon per hour .
(at least in an super ideal world .... )


cxa LPP.JPG
 

stardustsailor

Well-Known Member
The ones you got the spreadsheet ..

In block AA5 (total % of Qnt Flux ) ,
add to the math of the block " +AB5 "

So to be " = SUM(O5:Z5)+AB5 "

(in order to show a sum of 100% ) ..
A minor bug ....

Cheers .
 

stardustsailor

Well-Known Member
And some info for the Vero29 4000K CRI 80 ....

If we assume that Tc = 50C .....
Then from digitized values from this graph ...


vro vf vs Tc.JPG



At 1400mA If Vero29 will have a Vf of ~38,2 VDC
vf digitised.JPG





1.4* 38,2 = 53,48 Watts (electrical Power )

.....................................................................

Max Lumens value of Vero29 4000K is 10260 lm .(typical ,used as reference )
Digitising this graph ...
vero29 4000K norm flux.JPG
At 1400mA vero29 4000K has the 68,85% of the 10260 lumens ....

So ,10260 * 0.6885 = 7064.01 lm

7064.01 lm / 53,48 Watts = 132.0869 lm/W ..

132.0869 / 325 = 0,4064 ( => 40,64% efficiency )

0,4064* 53,48 Watts= 21,7354 Watts of light power ...

53,48 Watts - 21,7354 Watts = 31,7445 Watts of heat ....

Tj =Tc + (Q* Rθj_c ) =>
Tj = 50 + ( 31,7445 * 0,25 )= ~58 C (57,9361 )

Continuing further and digitising this graph now ....
flux vs Tj vero29 4000K.JPG


tj vs lm digi.JPG




Value obtained is ~95% ....

Thus 7064.01 lm * 0.95 = 6710.8095 lm

Estimated Radiometric Efficiency is 125,5 lm / W / 325 = 0.3861
( 38,61% )
 

stardustsailor

Well-Known Member
plant and light.JPG


Green line : Intact Leaf's Absorptance. ( 1=100% , 0 =0% )
(Averaged values ,obtained from a wide range of plant species ,leaf size, age ,LAI and position )

Red line : Photosynthesis Action Spectra. Aka Relative Quantum Yield (RQE ) .( 1=100% , 0 =0% )
(Averaged over a wide range of plant pecies.Indoor/Chamber grown )

Yellow line : The above two factors ,combined (multiplied between ).. ( 1=100% , 0 =0% ) .
Photosynthetic Efficiency of plants per nm .


Highest values at 621-626 nm ,with a combined Absorptance-RQE factor of 88%:

(Look at first column for the wavelength and at the last- violet/blue- column for the values combined ...
Absorptance values per nm is the first from left violet column and RQE values are the next one -also violet colored )

values 1.JPG
values 2.JPG
values 3.JPG
 

MrFlux

Well-Known Member
That looks very impressive SDS, I'm glad that you'll be doing the analysis from now on :-)

For reference these are my numbers for the CXA 3000K:
Code:
CXA 3000K
Power in        : 3.76 W (9.40V x 0.40A)
Luminous flux   : 457 lumen
Efficacy        : 122 lumen/W
LER             : 328 lumen/W
Radiometric eff.: 37.1%
Radiant flux    : 1.39 W
Rel.quantum eff.: 86.5%  (McCree 1972 RQE data)
Photon flux     : 6.80 umol/s (1.81 umol/J, RQE adjusted 1.56 umol/J)
PPF             : 6.50 umol/s (1.73 umol/J)
420-480 nm blue : 10.0% power, 7.9% photons
620-680 nm red  : 24.2% power, 26.9% photons
Lux to photons  : 67.3 lux:umol/m2/s
As you can see I've dabbled with the McCree relative quantum efficiency (RQE) too; However it doesn't seem relevant at all. It was measured with monochromatic low intensity light, but everything changes when you use 1) white light 2) high intensity light. PPF (in umol) tells a much better story, together with...

Blue light. I used only the range of blue that has the most morphological effect. The 420-480nm range is based on this action spectrum:
blue-action.png
(source)

Finally, you can see a "Lux to photons" number of 67.3. With this number everyone with a lux meter is now also the proud owner of a PAR meter. Simply divide the number of lux by 67.3 to get the PAR (in umol/m2/s). For example, 50,000 lux would correspond to 740 umol. Well at least in theory, and only for the CXA 3000K spectrum.
 

stardustsailor

Well-Known Member
And the CXA Relative Power Spectra vs the plant's photosynthetic efficiency spectra..
The latter normalised to 100% . A Normalised 100% equals to 88% Absolute Factor .

CXA vs plant efficiency Norm.JPG
 
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