Same reason it cant be calcium..calcium is an immobile nutrient, problems won't appear half way down the plant first! Also, the specs wouldn't just be on the veins for a calcium deficiency. Not to mention, if calcium is lacking, the root zone becomes acidic fast and there would be a host of other problems showing! The reason cal/mag is so popular, is because people have issues with ph often times, and adding cal mag, can fix the ph issue over time, but its not the actual element of calcium or magnesium that's lacking..it's just that those 2 cations have the greatest attraction to the cec sites in your medium..so if the cec sites are occupied by say too much potassium or iron or aluminum if ph has gone too low, then calcium and magnesium can help re-populate those sites by knocking those ions off and replacing them, and in turn, correcting the ph over time. His issue though is not a ph issue as again, the whole plant would be affected.