I havent found anything that actually works, and is safe to use. Roots can get through anything other than open air.
Copper is relatively safe to use in fresh water systems, but our nutes are salt based and will corrode the copper much faster.
As far as I know, no one has tested buds for excess copper content due to the use of these disks or copper mesh, etc, so maybe you are safe. Obviously, the guys using the disks have not had all their plants die either.
But when I read that most of the plant AND animal life in a huge portion of an ocean harbor had pretty much all died off due to copper from boat hulls, that was enough for me.