mirrors reflect rather than absorb light. In fact, they are near-perfect reflectors (95%). Too perfect, they concentrate light into pinpoints creating hot-spots that will burn and wither plants. If you are interested in learning more the property is specular reflectivity.
my opinion is mylar (92%) is best but expensive.
flat white paint (70%-80%) is a very, very, very close second best because it is also very reflective, cheap and comes in a heat proof/resistant version.