In theory RO is 7.0
This is very hard to measure
since there are no free ions in pure H2o
We are measuring the potential of Hydrogen(pH) ions
that are free in the solution.
Pure H2o has no free ions
since they are all bound up with the oxygen ions
Your probe contains a either a silver cathode reference wire element,
or silver ion electrolyte reference fluid.
In iether case, your probe will give up ions
to the ion free RO water.
Giving up these reference ions
will slow the response time of your meter
and make your calibrations inaccurate.
It is just good practice
to avoid letting your probe come into contact
with low ion fluids such as RO or distilled water.
Always keep your probe wet with saltwater
or nutrient solution,
or pH 4 calibration fluid.
You can make you own storage fluid with table salt and RO
Just check it often to make sure it does not dry out.