Hi mate. i had the same problem when i started my grow. Not realising why this was, i did some research to fix the problem... Here is what i found out and what it was being caused by and fixing the problem. So i hope this help's you as it did with me.
Firstly when your lights are on the heat generated by them will dry the air in the grow space keeping the humidity lower. At night cycle the heat is no longer in abundance so the humidity is not being dried and will stay at a lower level in the grow room. Thus causing buds to rot or on early plant leaf mold. Now i had a couple of fans going at night and a 6" carbon filter. This should have meant that my humidity should have stableised within the room but as the grow went on the humidity became even higher. I started scratching my head again and to look for an alternative solution to lowering the humidity, so i went and got a dehumidifier at a pricely cost. Now me being me. I knew that this would do the job. I put it in the room at night and hey presto it sucked moisture from the room. But somthing still didn't seem right as it only lowered it by 10% ish and for the next few days i monitored the humidity.
After a few days. I started thinking that it was somthing else and to start checking the equipment that i have. This is what i found was the problem.
After checking all fans were working properly i started to check the ducting that was fixed to the exhaust and found that the condensation had built up so much in side the duct that it had created a pool of water inside, this was stopping the humidity exiting the room. So what i did was to drain the ducting, re-fix it with less bends and to get a pin and prick some tiny holes in it where the condensation may collect, so that if water drops do form and collect then they have somewhere to get out from. I put a few towels under this so i could test this method and it worked...
I took out the dehumidifier at night and tested the room and it was bang on perfect on the first test. So if your using ducting it may be wise to just give it a little check to see if there is a build up of liquid...
Sorry this was a bit of a read for you but if there is anything in there that may help you then your good to try it......
Dan