if the ph is off, id seriously worry about what might be getting into the creek upstream from you... like to the point where i wouldnt just adjust it with ph up/down because of what could be in it. maybe roll up a

fatty

and take a walk upstream to check it out? depending on who might be up there this might not be a great idea though... neem can clog the stomata on the leaves, so make sure to use a diluted solution in water with drop or 2 of dish soap as an emulsifier. oh and ya... if you find the ph is off try to flush it with water you already know is clean and in the correct ph range.
good luck and give an update once youve checked it out!