Honestly couldn't give you the figures on ideal for co2 , but generally you get better transpiration over 80f without it and as im aware the use of co2 usually calls for higher than normal temps I figure your a bit low with or without co2.
Going on my own experience with LED in veg I know it was the biggest factor in keeping plants happy and when keeping temps up was difficult in the dead of winter the next major factor was to reduce light hours (obviously veg period) these things made the world of difference in plant looking happy and uptaking nutrients.