im asuming your in soil...
first of all you shouldnt be feeding and/or watering every day...going to cause root rot problems unless your containers are drying out completly that quick which can happen but is un common.
if you are PHing your water/nutrient solution you shouldnt have to worry about testing the soil, as far as ppm/ec you should just have to test your solution once and know that x amount of nutrient solution in y amount of water gives z ppm. fill your watering container up, add a measured incriment. 1 tsp of nutrient solution..measure ppm now you have a base PPM counting any particles in the water you use..so say 1 tsp gives you a ppm of 450 in a 1 gal container.
then add another tsp of nutrient....now test ppm of water again...now you have 750 ppm.... so now you know that each tsp of nutrient solution raises the ppm of 1 gallon of water by 300 and your plain water probably has a ppm of around 150...if your not convinced add another tsp of nutrient and measure...should give you a ppm of 1050 +/- (theres no way it will be dead on but should be within 100 ppm +/- )
you will check your PPM/EC with a ppm pen....you can check runoff ppm but not really worthwhile, if your using chemical nutrients then you will want to flush your containers every 6 weeks with plain water = to 5x the container size...i.e a 3gal pot would get flushed with 15 gal of plain water. this will wash out any salt build up and keep you protected against lockout issues due to buildup...its not always necessary but a good preventitave measure.
so to answer your ??
1) yes, check ph of nutrient solution and adjust as needed before watering. doing this will ensure you maintain a good ph level in your soil. if you dont adjust the soil PH may change over time.
2) PH of runoff is irrelivant but if your soil starts off at the correct PH and you are PHing your nutrient solution before watering/feeding then the runoff should be pretty close to your desired level.
i think i covered all of it..