Ah, this one bugged me while I was somewhere else.
Vostok the Sith Lord is correct bottom line for the coloration/necrotization . That's text book nute burn on the upper growth. Low ppm's be damned. You got something going on besides the Heat/moisture stress of the cupping leaves!!!! Get the heat off the canopy as their fighting to transpire enough. That in turn maybe bringing up to many nutes to the top of the plant causing your burn problem.
To explain that I would say this. The cupping of the leaves is technically moisture stress. This problem is that their not getting enough to transpire correctly. It looks like that maybe caused by to high a heat at the canopy level. This could be coupled with a low hanging light giving off to much heat at the canopy level also. When this happens the plant try's to transpire faster to lower it's temps at the problem area. This in turn brings up nutrients at an increased rate to the effected level. What happens next is the nute burn we're seeing in that area!!!!!
So,,,,cool down the canopy level and maybe raise the light a tad to help that and follow the refill suggestion and that should cure the problem.....