There also exists a balance among the major cations, K, Ca, and Mg, and
if these elements are out of balance with each other, then Ca uptake and
movement can be impaired. The author has observed BER-affected fruits when
there were visual leaf Mg-deficiency symptoms. The presence of NH4 in the
nutrient solution, if greater than 10%, can significantly increase the incidence
of BER (Hartman et al., 1986).
Phosphorus excess is more likely to occur than its deficiency, and its excess
(greater than 1.00% of the dry weight) in recently mature leaves can result in
Zn deficiency (Jones, 1998a).
The source of Fe can not only affect its uptake but can significantly impact
the plant. For example, the chelate ethylenediaminetetrateacetic acid (EDTA)
Figure 11.25 Symptoms of blossom-end rot (BER) on tomato fruit. Normally,
the symptom — browning (decay) of the blossom end of the fruit — occurs
early in fruit development. Such fruit should be removed when first observed.
BER fruit will early turn red.
Hydroponic Cropping 215
form of Fe is not recommended since EDTA is toxic to the plant (Rengel,
2002). The chelate diethylenetriaminepentaacetic acid (DTPA) form of Fe is
the accepted chelated form since DTPA toxicity is thought not to exist. Rengel
(2002) observed that the inclusion of Fe-EDTA in a nutrient solution resulted
in reduced uptake and translocation of the micronutrients Cu and Zn within
the plant. It is not known if the DTPA form of chelated Fe will have the same
effect on these two micronutrients. Other chelated forms of Fe, HEEDTA, NTA,
and EDDHA, have been used, but to a lesser degree than either EDTA or
DTPA. Several inorganic forms of Fe have been found suitable as Fe sources
in nutrient solution formulations, such as iron ferrous sulfate, FeSO4•7H2O;
iron ferric sulfate, Fe2(SO4)3; ferric chloride, FeCl3•6H2O; and iron ammonium
sulfate, FeSO4(NH4)2SO4•6H2O.
The author has frequently observed low Cu and Zn contents in tomato
leaf samples submitted for analysis and interpretation. The questions that need
to be answered are, “do these low levels reflect an inadequate amount of Cu
and Zn in the nutrient solution,” or “is it a factor related to cultivar adsorption
capacity, or is it the influence of the Fe chelate in the nutrient solution on
Cu and Zn adsorption?” My best guess would be the influence of the presence
of the chelate in the nutrient solution. In earlier experiments, I have found
that if the Fe source was an inorganic one (see pages 57 and 39

, low Cu
and Zn leaf contents were not frequently observed.
Under varying environmental conditions, the nutrient element