You cant have calcium absorption with a ph below 6 that's why I said let it drift before you change it. OR your plants could be sweating causing water to pool up. then the light comes on and fries them. Open the tent just before the lights come on and check for wet leaves. DO YOU HAVE A FAN?
Are you saying there is in abundance of calcium because the plants aren't using it due to the ph being below 6.0 which is locking out magnesium causing the rust spots?